全文获取类型
收费全文 | 553篇 |
免费 | 33篇 |
国内免费 | 1篇 |
专业分类
化学 | 420篇 |
晶体学 | 14篇 |
力学 | 9篇 |
数学 | 38篇 |
物理学 | 106篇 |
出版年
2021年 | 2篇 |
2020年 | 8篇 |
2019年 | 4篇 |
2018年 | 13篇 |
2017年 | 6篇 |
2016年 | 10篇 |
2015年 | 14篇 |
2014年 | 11篇 |
2013年 | 34篇 |
2012年 | 22篇 |
2011年 | 31篇 |
2010年 | 21篇 |
2009年 | 16篇 |
2008年 | 52篇 |
2007年 | 30篇 |
2006年 | 32篇 |
2005年 | 29篇 |
2004年 | 26篇 |
2003年 | 20篇 |
2002年 | 18篇 |
2001年 | 4篇 |
2000年 | 2篇 |
1999年 | 3篇 |
1998年 | 6篇 |
1997年 | 3篇 |
1996年 | 8篇 |
1995年 | 5篇 |
1994年 | 4篇 |
1993年 | 6篇 |
1992年 | 7篇 |
1991年 | 4篇 |
1990年 | 4篇 |
1989年 | 2篇 |
1988年 | 5篇 |
1987年 | 2篇 |
1986年 | 7篇 |
1985年 | 6篇 |
1984年 | 9篇 |
1983年 | 7篇 |
1982年 | 11篇 |
1981年 | 12篇 |
1980年 | 12篇 |
1979年 | 7篇 |
1978年 | 9篇 |
1977年 | 13篇 |
1976年 | 7篇 |
1975年 | 6篇 |
1974年 | 5篇 |
1973年 | 2篇 |
1962年 | 2篇 |
排序方式: 共有587条查询结果,搜索用时 31 毫秒
91.
92.
Amphidinol 3 (AM3) exhibits a potent membrane permeabilizing activity by forming pores in biological membranes. We examined the conformation and location of AM3 using isotropic bicelles, a more natural membrane model than micelles. The results show that AM3 takes turn structures at the two tetrahydropyran rings. Most of the hydrophilic region of the molecule is predominantly present in the surface, while the hydrophobic polyolefin penetrates in the bicelle interior. 相似文献
93.
Yamada M Wakahara T Lian Y Tsuchiya T Akasaka T Waelchli M Mizorogi N Nagase S Kadish KM 《Journal of the American Chemical Society》2006,128(5):1400-1401
The mapping of bond connectivity in the carbon cage of [Ce@C82]- and full assignment of the NMR lines were successfully achieved by means of 2D INADEQUATE NMR measurement. Paramagnetic NMR analysis shows that the Ce atom in [Ce@C82]- is located at an off-centered position adjacent to a hexagonal ring along the C2 axis of the C2v-C82 cage. 相似文献
94.
[structure: see text] Covalently linked dimers of amphotericin B were prepared by cross-linking its carboxylic acid. Among these, a dimer with a linkage of 1,6-hexanediamine revealed potent hemolytic activity (EC50, 0.25 microM) while its N-acetyl derivative gave rise to large K+ ion flux in phosphatidylcholine liposomes, regardless of the presence or absence of sterols, suggesting that the dimers may serve as a tool for elucidating the structure of the ion channel assemblage formed by amphotericin B. 相似文献
95.
Shigendo Enomoto Ken-ichi Kumagai Taro Tamura Miki Hasegawa Kyoko Nakada Toshihiko Hoshi Michio Kobayashi 《Monatshefte für Chemie / Chemical Monthly》2004,29(1):471-481
Fluoranthene (FA) forms a 1:1 van der Waals complex with benzene in cyclohexane. The 1H NMR spectrum of this complex shows that the FA moiety in the complex state has five kinds of hydrogen atoms and that the 1H NMR peaks assigned to the protons attached to the naphthalene skeleton are largely shifted to higher magnetic field on complex formation with benzene. These observations indicate that the complex takes the structure of CS symmetry, in which the benzene molecule mainly interacts with the electronic system localized on the naphthalene moiety of FA. The present ab initio calculations reproduce well the 1H NMR spectral shifts mentioned above and the experimentally predicted CS structure of the complex. According to the PPP calculations for the electronic absorption spectral changes on the complex formation, the FA-benzene complex is considered to take a sandwich type structure. 相似文献
96.
97.
In two-flavor dense quark matter, we describe the dynamics in the single plane wave Larkin-Ovchinnikov-Fulde-Ferrell (LOFF) state satisfying the color and electric neutrality conditions. We find that because the neutral LOFF state itself suffers from a chromomagnetic instability in the whole region where it coexists with the (gapped or gapless) two-flavor superconducting phases, it cannot cure this instability in those phases. This is unlike the recently revealed gluonic phase which seems to be able to resolve this problem. 相似文献
98.
Akane Sato Mizuho Okada Kazuya Saito Michio Sorai 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(5):564-565
In the crystal structure of the title charge‐transfer complex, namely trans‐stilbene–2,2′‐(2,3,5,6‐tetrafluorobenzene‐1,4‐diylidene)propanedinitrile (1/1) (trans‐STB–TCNQF4), C14H12·C12F4N4, the planar STB and TCNQF4 molecules are stacked alternately. The structure is not isostructural with that of STB–TCNQ. No anomaly was found in the displacement parameters of any atoms, while the bond length of the central C=C moiety was shorter than the corresponding bond in ethylene. This suggests that the central C=C moiety of the STB molecule vibrates with a large amplitude, similar to the case in free STB and STB–TCNQ. 相似文献
99.
Y Yamamoto K Fukatsu H Nishiyama 《Chemical communications (Cambridge, England)》2012,48(64):7985-7987
The first catalytic synthesis of exocyclic 1,3-dienylphosphine oxides was achieved by the ruthenium-catalyzed selective hydrophosphinylative cyclization of 1,6-diynes. A plausible mechanism involving a ruthenacyclopentatriene intermediate is proposed on the basis of the DFT calculations of model ruthenium complexes. 相似文献
100.
In order to evaluate the effect of annealing treatment on the proton conductivity of ??-alumina, the electrical conductivity of Mg-doped polycrystalline ??-alumina kept at 1,873?K under various conditions of the surrounding atmosphere and then cooled in the furnace was measured in the temperature range 1,173?C1,473?K. The H+/D+ isotope effect on the electrical conductivity was also examined under a hydrogen atmosphere at 1,273?K. The protonic conductivity measured at 1,273?K increased with the increase in the activity of oxygen and water vapor in the annealing atmosphere at 1,873?K. It is considered that the solubility limit of magnesium ions in ??-alumina in equilibrium with the small amount of the spinel phase increased with the increase in the activity of oxygen and water vapor at 1,873?K. This enhanced amount of magnesium ions is frozen in a non-equilibrium state to 1,273?K and works as the enriched acceptor dopant for the incorporation of protons. 相似文献